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You cannot add an attachment to an e-mail message as part of the mail-merge operation in Word
Article ID: 839372 - View products that this article applies to.
When you perform a mail merge to send an e-mail message in Microsoft Office Word, you cannot add an attachment to the e-mail message as part of the mail-merge operation.
To work around this behavior, publish the attachment to a Web site on the Internet. After you do this, provide the path link for the attachment in the body of the merged document that you are sending.