Personal folder files are unsupported over a LAN or over a WAN link Explains why personal folder files are unsupported over a LAN or over a WAN link. .PST files are created to store messages locally. To resolve the issue, you can use Exchange Server with .ost file or Terminal Services instead of .PST over a LAN or WAN.
How to compact the personal folders (.pst) files in Outlook Describes how to compact the personal folders (.pst) files in Outlook to conserve space on your hard disk. You can delete unwanted items from the various .pst folders, and then compact the files to make them smaller.