Chat keeps track of people you've chatted with, and you can search more. The list is not the same as the phone contacts list.
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On the left pane, select Chat.
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Choose New chat at the top of the Chat column.
Note: When a new chat first opens, there are a list of past contacts below the To: field. -
Select the To: field and type a name to find.
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Choose the name you want and start chatting.
To view or find phone contacts, see View or find your phone contacts.