Sign into Microsoft Edge
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With the Edge browser launched, select Profile > Sign in to sync data.
             
Create multiple profiles
With Edge Chromium, you can add multiple profiles. Profiles allow multiple users to operate in a shared environment while maintaining access to their personalized browser settings, bookmarks, and extensions.
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Select Profile, then choose Manage profile settings.
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Select + Add profile.
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Select Add.
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Sign in to sync data, to connect to an existing account, then select Continue.
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Use the slider to toggle sign in synchronization to Yes, then select Confirm.
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The additional profiles are now available for selection.