Educators are team owners and can remove other educators from a class team. Removing another educator removes their owner permissions in the team.
Remove an educator
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Navigate to a class team and select More options > Manage team.
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Navigate to the educator you're removing and change their role from Owner to Member by selecting the downward arrow.
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Now, select the X at the end of the educator's row underneath Members and guests. The educator will be removed from your class.