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On the Mailings tab, selectÂ
  Envelopes. -
Type a Delivery address and a Return address in the boxes.
Tip:Â Select Options to change the envelope size, font, and printing direction.
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Select the Feed box to position a blank envelope in the printer tray and select Print.
Printing an envelope isn't currently possible in Word for the web. You can, however, print an envelope in the Word desktop app.
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To open the desktop app, at the top of the ribbon, select Editing > Open in Desktop App.
Don't have the Word desktop app? Try or buy Microsoft 365.
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On the Mailings tab, selectÂ
  Envelopes. -
Type a Delivery address and a Return address in the boxes.
Tip: Select Font, Position, or Page Setup for addition options.
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Select Print to choose printer options, and then choose Print.