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Select the File menu and select Options.
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On the General tab, under Personalize your copy of Microsoft Office, select the Office Theme drop-down arrow and select an option.
Word's dark mode will be automatically enabled depending on MacOS settings. To check if you have dark mode enabled at the system level:
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From the
 Apple icon, select System Settings and choose Appearance, -
Select Dark or Auto.
To set dark mode specifically for Word:
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Select Preferences and choose General.
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Select or clear Turn off Dark Mode.
Note: If Dark mode is on for the system, this turns it on or off only for Word
To toggle dark mode on or off, on the View menu, select Dark Mode.